Select orange as background colour
Select blue as foreground colour
Select from the menu Image->Adjustments->Gradient Map. Unfold the drop-down and make sure the first gradient option is selected (from foreground to background).

Note: You might want to do some prep work first and exaggerate the contrast by playing with the levels. It might help turning the image grayscale first.

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: How to colorize highlights and shadows of a photo How is it possible to achieve the effect created in this photo: Any help is much appreciated!

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